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  5. METHODS, TECHNIQUES AND TECHNOLOGIES OF NEUTRALIZATION AND DISPOSAL OF HAZARDOUS PERSISTENT ORGANIC POLLUTANTS

METHODS, TECHNIQUES AND TECHNOLOGIES OF NEUTRALIZATION AND DISPOSAL OF HAZARDOUS PERSISTENT ORGANIC POLLUTANTS

Section

Environmental Safety Construction and Town Economy

Title

METHODS, TECHNIQUES AND TECHNOLOGIES OF NEUTRALIZATION AND DISPOSAL OF HAZARDOUS PERSISTENT ORGANIC POLLUTANTS

Сontributors

E. A. Pichugin, Deputy Head of Department environmental problems FGBU UralNII “Ecology ”, This email address is being protected from spambots. You need JavaScript enabled to view it.

Abstract

It is shown that one of the most serious environmental problems is now utilization of the resistant organic pollutants (ROP) since these chemicals don't decay or slowly decay under natural conditions and do to environment components essential harm. According to the Stockholm Convention, ratified by the Russian Federation, the most hazardous substances are the 12 persistent organic pollutants: pesticides (dichloro-diphenyl-trichloroethane (DDT), aldrin, dieldrin, endrin, chlordane, mirex, toxaphene, hep- tachlor); Industrial chemicals (polychlorinated biphenyls (PCBs), hexachlorobenzene (HCB), by-products (polychlorodibenzodioxins (PCDDs), polychlorinated dibenzofurans (PCDF). In this paper, the author conducted an analytical review and analysis of the scientific and patent literature on the methods of disposal persistent organic pollutants. According to the analysis revealed that at present the most widely used methods of disposal are thermal and complex methods.

Keywords

persistent organic pollutants, disposal, environment, environmental pollution, pesticides, industrial substances, methods of disposal, thermal methods of disposal, complex methods of disposal.

References

1.  “Persistent organic pollutants: a global problem, a global solution”, available at: http://www.unido-rus- sia.ru/archive/num_14/art14_5/ (accessed 13 June 2016).

2.  “International Project on POPs Elimination. Persistent organic pollutants: a review of the situation in Russia”, available at: http://www.ecoaccord.org/pop/ipep/russia-review.htm, www.ipen.org (accessed 13 June 2016).

3.  Federal Law of 27.06.2011 number 164-FZ “On the ratification of the Stockholm Convention on Persistent Organic Pollutants”, available at: Access from sprav. legal system “Techexpert”.

4.  Public corporation “UKRDITSEMENT”, available at: http://waste.ua/old/recycle/ukrditcement.html (accessed 16 June 2016). 

5.  Gavrilov R. V., Smooth V. V., Beskorsy A. P., Postnikov V. A., Kostenko O. V. An alternative method for the destruction of highly toxic waste, available at: http://waste.ua/cooperation/2005/theses/gavry- lov.html (accessed 16 June 2016).

6.  Ryzhavsky A. Z., Zimoglyad A. V. Installing of thermal neutralization of toxic chemicals, available at: http://waste.ua/cooperation/2007/theses/rizhavskiy.html (accessed 16 June 2016).

7.  “Sovtolovye transformers and their disposal — circuit design and appointment the main elements of the transformer”, available at: http://leg.co.ua/transformatori/teoriya/shemy-konstrukciy-i-naznachenie-os- novnyh-elementov-transformatora-10.html (accessed 17 June 2016).

8.  Limited Liability Company “ELFA”. Neutralization supertoxicants, available at: http://www.ecoelfa.ru/ rus/technology.htm (accessed 17 June 2016).

9.  Assaulyuk S. A., Sapunov A. U., Shchepkin M. V.; Mikhailov O. V., Bozhko S. V. (2008), The process of neutralization of substandard pesticides thermochemical method and installation for plasma-chemical disposal of pesticides, available at: http://www1.fips.ru/wps/portal/IPS_Ru (accessed 23 June 2016), Russia, The application for invention No. 2006 131 631.

10. “Installation for plasma chemical treatment of liquid organic and organochlorine industrial waste”, available at: http://www.new-garbage.com/?id=668&page=110&part=14#.V3YtIxIxFUU (accessed 17 June 2016).

11. “Mosse A. L., Simon Y., Savchin V. V., Zinovenko I. N. Mobile plasma system for the destruction of toxic halogenated organic waste”, available at: http://waste.ua/cooperation/2007/theses/mosse.html (accessed 21 June 2016).

12. Bukov N. N., Repnoe L. F., Laktionov A. I., Assaulyuk S. A., Sapunov A. Yu., Panyushkin V. T. (2007), [Pesticides disposal of Method], available at: http://www1.fips.ru/wps/portal/IPS_Ru (accessed 23 June 2016), Russia, The application for invention No. 2005 135 514.

13. Kononov O. A. Recycling organochlorine wastes productions by catalytic oxidation // Ecology and Industry of Russia, — 2003. — No. 1. P. 8—11.

14. “Catalytic processes in the Chlorine Organic Synthesis (II part)”, available at: http://www.newchemis- try.ru/printletter.php?n_id=1414 (accessed 21 June 2016).

15. Gorbunova T. I., Pervova M. G., Zabelin O. N., Saloutin V. I., Chupahin O. N. Polychlorinated biphenyls: Ecological problems, analysis and chemical recycling. — Publishing HOUSE KRASAND, — Ural Branch of the Russian Academy of Sciences. — 2011. — 400 p.

16. “Technology processing and recycling of toxic chemicals and pesticides”, available at: http://refdb.ru/ look/1217987.html (accessed 14 June 2016).

17. Brodsky E. S., Yevdokimov G. V., Zlotin S. G., Klyuev N. A., Samsonov D. P., Shinkova N. A., Yufit S. S. Disposal of electrotechnic fluids containing polychlorinated biphenyls — Green Chemistry in Russia. Collection of articles. Publishing House of the Moscow university, 2004. — P. 163—184.

18. Zalimov T. R., Yagafarova G. G., Zalimova K. R. Method for processing waste organochlorine liquid- phase catalytic hydrochlorination, available at: http://www1.fips.ru/wps/portal/IPS_Ru (accessed 22 June 2016), Russia, — Pat. No. 2458030.

19. Zanaveskin K. L. (2011), Catalytic hydro-dechlorination polychlorobenzenes and polychlorinated biphenyls, Abstract of Cand. Chem. Sci. dissertation, Organic substances technology, Russian Chemical-Technological University. D. I. Mendeleev, Moscow, Russia, available at: http://www.dslib.net/texnologia- sinteza/kataliticheskoe-gidrodehlorirovanie-polihlorbenzolov-i-polihlorbifenilov.html (accessed 22 June 2016).

20. Sedov J. A., Mayorov S. A., Parahin Y. A., Closed Joint Stock Company “Ecology” (2009), Sposob uti- lizacii nekondicionnykh pesticidov [Method of disposal of of substandard pesticides], available at: http:// www1.fips.ru/wps/portal/IPS_Ru (accessed 22 June 2016), Russia, Pat. № 2360721.

21. Kapranov V. V., Zharikov G. A., Dyadischev N. R., State Institution Research Center for Toxicology and Hygienic Regulation of Biopreparations at the Federal Office of Biomedical and Extreme Problems Russian Health Ministry, Shtamm drozhzhej hansenulla californica razlagayushhij polikhlorirovannye bifenily [Yeast strain hansenula californica, decomposing polychlorinated biphenyls], available at: http:// www1.fips.ru/wps/portal/IPS_Ru (accessed 22 June 2016), Russia, Pat. No. 2155803.

22. Kapranov V. V., Zharikov G. A., Borovik R. V., State Institution Research Center for Toxicology and Hygienic Regulation of Biopreparations at the Federal Office of Biomedical and Extreme Problems Russian Health Ministry, Yeast strain alcaligenes latus, decomposing polychlorinated biphenyls, available at: http://www1.fips.ru/wps/portal/IPS_Ru (accessed 22 June 2016), Russia, Pat. No. 2155804.

23. Afanasyev V. N., Gamow M. V., Garankina N. G., Kruglov Yu. V., Maksimov D. A., Paromenskaya L. N., State Scientific Institution AIl-Russian Research Institute for Agricultural Microbiology. The process for producing microbial preparation for disposal pesticides, available at: http://www1.fips.ru/wps/portal/ IPS_Ru (accessed 22 June 2016), Russia, Pat. No. 2279325.

24. Soromotin A. V., Ogurtsova L. V., Morozova T. N., Zhdanova E. B., State Educational Institution of Higher Professional Education “Tyumen State University”. Method of microbiological destruction of organochlorine pesticides, available at: http://www1.fips.ru/wps/portal/IPS_Ru (accessed 24 June 2016), Russia, Pat. No. 2448786.